The mixed ionic–electronic nature of lead halide perovskites makes their performance in solar cells complex in nature. Ion migration is often associated with negative impacts─such as hysteresis or device degradation─leading to significant efforts to suppress ionic movement in perovskite solar cells. In this work, we demonstrate that ion trapping at the perovskite/electron transport layer interface induces band bending, thus increasing the built-in potential and open-circuit voltage of the device. Quantum chemical calculations reveal that iodine interstitials are stabilized at that interface, effectively trapping them at a remarkably high density of ∼1021 cm–3 which causes the band bending. Despite the presence of this high density of ionic defects, the electronic structure calculations show no sub-band-gap states (electronic traps) are formed due to a pronounced perovskite lattice reorganization. Our work demonstrates that ionic traps can have a positive impact on device performance of perovskite solar cells.

Quantum key distribution (QKD) protocols make it possible for two parties to generate a secret shared key. One of the most important QKD protocols, BB84, was suggested by Bennett and Brassard in 1984. Various proofs of unconditional security for BB84 have been suggested, but the first security proofs were not composable. Here we improve a security proof of BB84 given by [Biham, Boyer, Boykin, Mor, and Roychowdhury, J. Cryptology, 19(4):381-439, 2006] to be composable and match the state-of-the-art results for BB84, and we extend it to prove unconditional security of several variants of the BB84 protocol. Our composable security proof for BB84 and its variants is mostly self-contained, algebraic, and relatively simple, and it gives tight finite-key bounds.

The quantum chromodynamics axion with a decay constant near the Grand Unification (GUT) scale has an ultralight mass near a neV. We show, however, that axion-like particles with masses near the keV - PeV range with GUT-scale decay constants are also well motivated in that they naturally arise from axiverse theories with dark non-abelian gauge groups. We demonstrate that the correct dark matter abundance may be achieved by the heavy axions in these models through the misalignment mechanism in combination with a period of early matter domination from the long-lived dark glueballs of the same gauge group. Heavy axion dark matter may decay to two photons, yielding mono-energetic electromagnetic signatures that may be detectable by current or next-generation space-based telescopes. We project the sensitivity of next-generation telescopes including $\textit {Athena,}$ AMEGO, and e-ASTROGAM to such decaying axion dark matter. If the dark sector contains multiple confining gauge groups, then the observed primordial baryon asymmetry may also be achieved in this scenario through spontaneous baryogenesis. We present explicit orbifold constructions where the dark gauge groups unify with the SM at the GUT scale and axions emerge as the fifth components of dark gauge fields with bulk Chern-Simons terms.

We present a method for quantum tomography of multiqubit states. We apply the method to spin-multiphoton states, which we generate using a quantum dot based device. Periodic excitation of a quantum dot confined spin deterministically generates strings of entangled photons in a cluster state, threefold faster than previously demonstrated. Our tomography method uses time-resolved polarization-sensitive multiphoton correlation measurements to measure both the polarization of the confined spin and that of the emitted photons. We develop an edge-sensitive gradient-descent algorithm and apply it to the acquired data to map the periodic physical process that generates the cluster state. We utilize our tomographic method to optimize our quantum dot based device and show that the enhanced generation rate increases the entanglement robustness of the generated multiqubit state.

We report on the implementation of degenerate Raman sideband cooling of $^{40}$K atoms. The scheme incorporates a 3D optical lattice, which confines the atoms and drives the Raman transitions. The optical cooling cycle is closed by two optical pumping beams. The wavelength of the laser beams forming the lattice is close to the D$_2$ atomic transition, while the optical pumping is operated near the D$_1$ transition. With this cooling method, we achieve temperature of $\sim$$1\mu$K of a cloud with $\sim$$10^7$ atoms. This corresponds to a phase space density of $\ge$$10^{-3}$. Moreover, the fermionic ensemble is spin polarized to conditions which are favorable for subsequent evaporative cooling. We study the dependence of the cooling scheme on several parameters, including the applied magnetic field, the detuning, duration, and intensity profile of the optical pumping beams. Adding this optical cooling stage to current Fermi gas experiments can improve the final conditions and increase the data rate.

Copper-doped II–VI and copper-based I–III–VI₂ colloidal quantum dots (CQDs) have been at the forefront of interest in nanocrystals over the past decade, attributable to their optically activated copper states. However, the related recombination mechanisms are still unclear. The current work elaborates on recombination processes in such materials by following the spin properties of copper-doped CdSe/CdS ([email protected]/CdS) and of CuInS₂ and CuInS₂/(CdS, ZnS) core/shell CQDs using continuous-wave and time-resolved optically detected magnetic resonance (ODMR) spectroscopy. The [email protected]/CdS ODMR showed two distinct resonances with different g factors and spin relaxation times. The best fit by a spin Hamiltonian simulation suggests that emission comes from recombination of a delocalized electron at the conduction band edge with a hole trapped in a Cu²⁺ site with a weak exchange coupling between the two spins. The ODMR spectra of CuInS₂ CQDs (with and without shells) differ significantly from those of the copper-doped II–VI CQDs. They are comprised of a primary resonance accompanied by another resonance at half-field, with a strong correlation between the two, indicating the involvement of a triplet exciton and hence stronger electron–hole exchange coupling than in the doped core/shell CQDs. The spin Hamiltonian simulation shows that the hole is again associated with a photogenerated Cu²⁺ site. The electron resides near this Cu²⁺ site, and its ODMR spectrum shows contributions from superhyperfine coupling to neighboring indium atoms. These observations are consistent with the occurrence of a self-trapped exciton associated with the copper site. The results presented here support models under debate for over a decade and help define the magneto-optical properties of these important materials.

We study the effect of acoustic phonons on the quantum phase transition in the $O(N$) model. We develop a renormalization group (RG) analysis near $(3+1)$ space-time dimensions and derive the RG equations using an $\epsilon$ expansion. Our results indicate that when the number of flavors of the underlying $O(N$) model exceeds a critical number $N_c=4$, the quantum transition remains second-order of the Wilson-Fisher type while, for $N\le 4$, it is a weakly first-order transition. We characterize this weakly first-order transition by a length scale ${\xi }^{*}$, below which the behavior appears to be critical. At finite temperatures for $N\le 4$, a tricritical point separates the weakly first-order and second-order transitions.

Doped Mott insulators exhibit some of the most intriguing quantum phases of matter, including quantum spin liquids, unconventional superconductors and non-Fermi liquid metals^1,2,3. Such phases often arise when itinerant electrons are close to a Mott insulating state, and thus experience strong spatial correlations. Proximity between different layers of van der Waals heterostructures naturally realizes a platform for experimentally studying the relationship between localized, correlated electrons and itinerant electrons. Here we explore this relationship by studying the magnetic landscape of tantalum disulfide 4Hb-TaS₂, which realizes an alternating stacking of a candidate spin liquid and a superconductor⁴. We report on a spontaneous vortex phase whose vortex density can be trained in the normal state. We show that time-reversal symmetry is broken in the normal state, indicating the presence of a magnetic phase independent of the superconductor. Notably, this phase does not generate ferromagnetic signals that are detectable using conventional techniques. We use scanning superconducting quantum interference device microscopy to show that it is incompatible with ferromagnetic ordering. The discovery of this unusual magnetic phase illustrates how combining superconductivity with a strongly correlated system can lead to unexpected physics.